Configure Windows XP to
Automatically Login
Click Start, Run and type CONTROL
USERPASSWORDS2, and
click Ok.
Select the user account from the list
(the account to which you want to automatically logon).
Uncheck Users must enter a user name
and password to use this computer option, and click Ok.

Type the user account password and
complete the process.
For Windows XP Home, don't try to
auto-login as the built-in Administrator, as you'll receive an error
message.
OR
Automatic
Administrator Login
Well here's the trick which you can use to prove that Windows XP is
not at all secure as multi-user operating system. Hacking the system
registry from any account having access
to system registry puts you in to the
administrator account.
REGEDIT
[HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\Windows NT\CurrentVersion\Winlogon]
"AutoAdminLogon"="1"
or
Use
Tweak UI - Free Program |